Issue 20, 2000

A novel route to dithiolenes from 1,3-dithiole-2-thiones at a dicobalt centre

Abstract

On reaction with [Co2(μ-dppm)(CO)6] at room temperature, 4,5-bis(alkoxycarbonyl)-1,3-dithiole-2-thiones are dismantled into dithiolene and thiocarbonyl ligands by cleavage of two C–S bonds to give [Co2(μ-CS)(μ-S2C2R2)(CO)3(μ-dppm)] (R = CO2Me, CO2Et).

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2000
Accepted
06 Sep 2000
First published
19 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3489-3490

A novel route to dithiolenes from 1,3-dithiole-2-thiones at a dicobalt centre

H. Adams, L. V. Y. Guio, M. J. Morris and A. J. Pratt, J. Chem. Soc., Dalton Trans., 2000, 3489 DOI: 10.1039/B006052F

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