Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

Philip C. Andrews; Peter J. Duggan; Gary D. Fallon; Tom D. McCarthy; Anna C. Peatt

doi:10.1039/B003826L

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Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

Philip C. Andrews,*^a Peter J. Duggan,^a Gary D. Fallon,^a Tom D. McCarthy^b and Anna C. Peatt^a

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* Corresponding authors

^a Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, Australia
E-mail: p.andrews@sci.monash.edu.au

^b Biomolecular Research Institute, Private Bag 10, Clayton, Melbourne, Australia

Abstract

The reaction of (S)-{[(Ph(Me)CH)(PhCH₂)]NNa}_n with pmdeta (N,N,N′,N′,N′′-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na·pmdeta}, 3, and {[(PhCH)₂N]Na·pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.

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Crystal structure data TXT (32K)

Article information

DOI: https://doi.org/10.1039/B003826L
Article type: Communication
Submitted: 15 May 2000
Accepted: 22 Jun 2000
First published: 12 Jul 2000

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J. Chem. Soc., Dalton Trans., 2000, 2505-2507

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Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

P. C. Andrews, P. J. Duggan, G. D. Fallon, T. D. McCarthy and A. C. Peatt, J. Chem. Soc., Dalton Trans., 2000, 2505 DOI: 10.1039/B003826L

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Journal of the Chemical Society, Dalton Transactions

Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

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Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

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