Issue 18, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Formation of a gallium triphosphorus heterocycle by reaction of the alkylgallium(I) compound Ga4[C(SiMe3)3]4 with tri(tert-butyl)cyclotriphosphane

Werner Uhl*a  and  Maike Bentera  

* Corresponding authors

a Fachbereich Chemie der Philipps Universität Marburg, Hans-Meerwein-Straße, Marburg, Germany

Abstract

Tri(tert-butyl)cyclotriphosphane reacted with Ga4[C(SiMe3)3]41 by the insertion of a monomeric GaR fragment into one of its P–P bonds. A four-membered, slightly folded GaP3 heterocycle was formed which has a co-ordinatively unsaturated gallium atom and all substituents in trans positions.

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Article information

DOI
https://doi.org/10.1039/B003760P
Article type
Paper
Submitted
11 May 2000
Accepted
23 Jul 2000
First published
17 Aug 2000

J. Chem. Soc., Dalton Trans., 2000, 3133-3135

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Formation of a gallium triphosphorus heterocycle by reaction of the alkylgallium(I) compound Ga4[C(SiMe3)3]4 with tri(tert-butyl)cyclotriphosphane

W. Uhl and M. Benter, J. Chem. Soc., Dalton Trans., 2000, 3133 DOI: 10.1039/B003760P

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