Issue 14, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and X-ray crystal structure of an unexpected neutral oxalate-bridged ytterbium(III) porphyrinate dimer

Wai-Kwok Wong,*a   Li-Lu Zhang,a   Feng Xueb  and  Thomas C. W. Makb  

* Corresponding authors

a Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, P.R. China
E-mail: wkwong@hkbu.edu.hk

b Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, P.R. China

Abstract

Treatment of 5,10,15,20-tetraphenylporphyrin (H2tpp) with an excess of YbIII[N(SiMe3)2]3·x[LiCl(THF )3], generated in situ, in refluxing bis(2-methoxyethyl) ether solution, yielded the unexpected neutral oxalate-bridged dimer, [YbIII(tpp)(CH3OCH2CH2OCH3)]2(μ-η2∶η2-O2CCO2) 1, the structure of which was ascertained by X-ray crystallography.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B003434G
Article type
Communication
Submitted
28 Apr 2000
Accepted
14 Jun 2000
First published
27 Jun 2000

J. Chem. Soc., Dalton Trans., 2000, 2245-2246

Permissions

Request permissions

Synthesis and X-ray crystal structure of an unexpected neutral oxalate-bridged ytterbium(III) porphyrinate dimer

W. Wong, L. Zhang, F. Xue and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 2000, 2245 DOI: 10.1039/B003434G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements