Issue 13, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and molecular structures of a pair of tris(imidazolyl)phosphine cobalt–perchlorate complexes, {[PimPri2]Co(OClO3)}[ClO4] and {[PimPri2]Co(OH2)(HOMe)(OClO3)}[ClO4]

Clare Kimblin,a   Brian M. Bridgewater,a   David G. Churchilla  and  Gerard Parkin*a  

* Corresponding authors

a Department of Chemistry, Columbia University, New York, USA

Abstract

The cobalt–perchlorate complexes, {[PimPri2]Co(OClO3)}(ClO4) and {[PimPri2]Co(OH2)(HOMe)(OClO3)}(ClO4), have been synthesized via the reaction of tris[2-(1,4-diisopropylimidazolyl)]phosphine [PimPri2] with Co(ClO4)2·6H2O; the isolation of these species, as opposed to a hydroxide derivative {[PimPri2]CoOH}+, demonstrates the important role that steric interactions play in generating synthetic analogues for metal-substituted carbonic anhydrases.

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Article information

DOI
https://doi.org/10.1039/B002894K
Article type
Paper
Submitted
24 Jan 2000
Accepted
18 Apr 2000
First published
08 Jun 2000

J. Chem. Soc., Dalton Trans., 2000, 2191-2194

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Synthesis and molecular structures of a pair of tris(imidazolyl)phosphine cobalt–perchlorate complexes, {[PimPri2]Co(OClO3)}[ClO4] and {[PimPri2]Co(OH2)(HOMe)(OClO3)}[ClO4]

C. Kimblin, B. M. Bridgewater, D. G. Churchill and G. Parkin, J. Chem. Soc., Dalton Trans., 2000, 2191 DOI: 10.1039/B002894K

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