Issue 10, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Remarkable S,N,S ′ tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO

Pravat Bhattacharyya,a   Alexandra M. Z. Slawina  and  J. Derek Woollins*a  

* Corresponding authors

a Department of Chemistry, University of St Andrews, Fife, UK
E-mail: jdw3@st-andrews.ac.uk

Abstract

The reaction between [PdCl2(PhCN)2] and [Ph2P(S)NH]2C[double bond, length half m-dash]O (H2L) proceeds with monodeprotonation of an amine group in the disulfide ligand to give [Pd(HL)Cl] 1, in which the (HL)− anion supplies an S,N,S ′ donor set to palladium(II), leading to disparate S,N chelate ring sizes at the metal.

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Article information

DOI
https://doi.org/10.1039/B002413I
Article type
Communication
Submitted
27 Mar 2000
Accepted
11 Apr 2000
First published
02 May 2000

J. Chem. Soc., Dalton Trans., 2000, 1545-1546

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Remarkable S,N,S ′ tridentate chelation to palladium(II) by the monoanion derived from [Ph2P(S)NH]2CO

P. Bhattacharyya, A. M. Z. Slawin and J. D. Woollins, J. Chem. Soc., Dalton Trans., 2000, 1545 DOI: 10.1039/B002413I

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