Issue 15, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Two new one-dimensional systems with end-to-end single dicyanamide bridges between manganese(II) centres: structural and magnetic properties

Albert Claramunt,a   Albert Escuer,a   Franz A. Mautner,b   Núria Sanza  and  Ramon Vicente*a  

* Corresponding authors

a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, Barcelona, Spain
E-mail: rvicente@kripto.qui.ub.es

b Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, Graz, Austria

Abstract

Dicyanamide, [N(CN)2]− (dca), formed monodimensional compounds of formula [Mn(μ1,5-dca)(NO3)(terpy)]n1 and [Mn(μ1,5-dca)(H2O)(terpy)]n[dca]n2 (terpy = 2,2′∶6′,2′′-terpyridine). X-Ray diffraction analysis revealed two one-dimensional systems with single dca bridges. The manganese atom in 1 is seven-co-ordinated, with a MnN5O2 pentagonal bipyramidal environment, whereas in 2 the manganese atom is six-co-ordinated. Susceptibility measurements of 1 and 2 indicate slight antiferromagnetic coupling.

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Article information

DOI
https://doi.org/10.1039/B002214O
Article type
Paper
Submitted
20 Mar 2000
Accepted
13 Jun 2000
First published
13 Jul 2000

J. Chem. Soc., Dalton Trans., 2000, 2627-2630

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Two new one-dimensional systems with end-to-end single dicyanamide bridges between manganese(II) centres: structural and magnetic properties

A. Claramunt, A. Escuer, F. A. Mautner, N. Sanz and R. Vicente, J. Chem. Soc., Dalton Trans., 2000, 2627 DOI: 10.1039/B002214O

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