Issue 11, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units

Yingjun Zhao,a   Maochun Hong,a   Weiping Su,*a   Rong Cao,a   Zhongyuan Zhou*b  and  Albert S. C. Chan*b  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: hmc@ms.fjirsm.ac.cn

b Open Laboratory of Chirotechnology and Department of Applied Biology and Chemical Technology, the Hong Kong Polytechnic University, Hong Hum, Hong Kong

Abstract

Reaction of CuCN with PPh3 and PPh4Br induced by the pyridine-2-thiolate anion in DMF resulted in a discrete hexanuclear [Cu(CN)(PPh3)2]6 (1) complex with a large hexagonal cavity and a polymer [(PPh4){Cu2(CN)3}]n (2) with a graphite-like lamellar structure, respectively.

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Article information

DOI
https://doi.org/10.1039/B002096F
Article type
Communication
Submitted
15 Mar 2000
Accepted
12 Apr 2000
First published
08 May 2000

J. Chem. Soc., Dalton Trans., 2000, 1685-1686

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Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units

Y. Zhao, M. Hong, W. Su, R. Cao, Z. Zhou and A. S. C. Chan, J. Chem. Soc., Dalton Trans., 2000, 1685 DOI: 10.1039/B002096F

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