Issue 3, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, solution and electrochemical behaviour of new aza-crown ethers derived from biphenyl

Ana M. Costero,*a   Elena Monrabal,a   Cecilia Andreu,a   Ramón Martínez-Máñez,b   Juan Soto,b   Miguel Padilla-Tosta,b   Teresa Pardo,b   Luis E. Ochandoc  and  José M. Amigóc  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Farmacia, Universitat de València, Vicente Andrés Estellés s/n, Burjassot, Spain

b Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, Valencia, Spain

c Sección Departamental de Geología, Facultad de Química, Valencia, Spain

Abstract

Macrocyclic ligands L1–L4 containing biphenyl units have been synthesized. Potentiometric and voltametric studies in the presence and the absence of transition metal cations have been carried out. The relationship between the conformation of the ligand and oxidation states has been also considered. The crystal structure of [HgL2(CN)2]·2Hg(CN)2 has been elucidated by X-ray diffraction techniques.

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Article information

DOI
https://doi.org/10.1039/A906342K
Article type
Paper
Submitted
04 Aug 1999
Accepted
13 Dec 1999
First published
27 Jan 2000

J. Chem. Soc., Dalton Trans., 2000, 361-367

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Synthesis, solution and electrochemical behaviour of new aza-crown ethers derived from biphenyl

A. M. Costero, E. Monrabal, C. Andreu, R. Martínez-Máñez, J. Soto, M. Padilla-Tosta, T. Pardo, L. E. Ochando and J. M. Amigó, J. Chem. Soc., Dalton Trans., 2000, 361 DOI: 10.1039/A906342K

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