Issue 1, 2000

Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry

Abstract

Although coordination of carboxamido nitrogen to Fe(III) center has been assumed to be improbable, research work during the past few years has demonstrated that Fe(III) complexes with ligated carboxamido nitrogens can be readily synthesized. The Fe(III)–Namido bond distances lie in the range of 1.8–2.2 Å in the various low spin and high spin Fe(III) complexes. These complexes are stable in aqueous media and their redox parameters indicate that the carboxamido nitrogens provide significant stability to the Fe(III) center.

Article information

Article type
Review Article
Submitted
30 Jun 1999
First published
11 Jan 2000

Chem. Soc. Rev., 2000,29, 69-74

Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry

D. S. Marlin and P. K. Mascharak, Chem. Soc. Rev., 2000, 29, 69 DOI: 10.1039/A905282H

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