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Issue 23, 2000
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The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

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Abstract

The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conversion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl complex is achieved using triphenylphosphine as reductant.

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Article information


Submitted
18 Aug 2000
Accepted
17 Oct 2000
First published
08 Nov 2000

Chem. Commun., 2000, 2301-2302
Article type
Communication

The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

L. Cheng, D. R. Powell, M. A. Khan and G. B. Richter-Addo, Chem. Commun., 2000, 2301
DOI: 10.1039/B006775J

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