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Issue 22, 2000
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New insights into the endo–exo stereoselectivity of the intramolecular Diels-Alder reaction of 1,3,8-nonatrienes

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Abstract

B3LYP/6-31G(d) theory predicts the experimental endoexo selectivity of intramolecular Diels-Alder reactions of C9-substituted 1,3,8-nonatrienes: the reactions are concerted but the transition structures are remarkably asynchronous.

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Publication details

The article was received on 08 Aug 2000, accepted on 27 Sep 2000 and first published on 01 Nov 2000


Article type: Communication
DOI: 10.1039/B006483L
Citation: Chem. Commun., 2000,0, 2213-2214

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    New insights into the endo–exo stereoselectivity of the intramolecular Diels-Alder reaction of 1,3,8-nonatrienes

    M. J. Lilly, M. N. Paddon-Row, M. S. Sherburn and C. I. Turner, Chem. Commun., 2000, 0, 2213
    DOI: 10.1039/B006483L

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