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Issue 15, 2000
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Novel aluminium– and gallium–nitrogen heteronorbornanes

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Abstract

Selective formation of 2,5-dialumina-3,6-diaza- and 2,5-digalla-3,6-diaza-norbornane is achieved by reaction of bis(lithiomethyl-methylamino)methane with dimethylaluminium and dimethylgallium chloride by simultaneous formation of two metal–carbon and two metal–nitrogen bonds accompanied by two ring closure reactions; the norbornane-basket structures are favoured over potential isomers containing three-membered rings and over polymeric aggregation.

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Publication details

The article was received on 05 May 2000, accepted on 16 Jun 2000 and first published on 06 Jul 2000


Article type: Communication
DOI: 10.1039/B003813J
Citation: Chem. Commun., 2000,0, 1393-1394

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    Novel aluminium– and gallium–nitrogen heteronorbornanes

    C. Lustig and N. W. Mitzel, Chem. Commun., 2000, 0, 1393
    DOI: 10.1039/B003813J

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