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Issue 11, 2000
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Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

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Abstract

C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)- carbene] complexes of molybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form novel chelated hepta-coordinated Fischer-type tricarbonyl- (bishalogeno)carbene molybdenum(II) and tungsten(II) complexes

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Publication details

The article was received on 16 Mar 2000, accepted on 17 Apr 2000 and first published on 16 May 2000


Article type: Communication
DOI: 10.1039/B002228O
Citation: Chem. Commun., 2000,0, 931-932
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    Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

    M. Jaeger, R. Stumpf, C. Troll and H. Fischer, Chem. Commun., 2000, 0, 931
    DOI: 10.1039/B002228O

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