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Issue 7, 2000
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The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxideAbbreviations TPTN = N,N,N′,N′-tetrakis(2-pyridylmethyl)propane-1 ,3-diamine, TPEN = N,N,N′,N′-tetrakis(2-pyridylmethyl)ethane-1, 2-diamine.

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Abstract

In acetone and at ambient temperature, the dinuclear manganese complex of TPTN is able to catalyse the oxidation of several alkenes to the corresponding epoxides with high turnovers numbers (up to 900) using H2O2 as oxidant.

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Publication details

The article was received on 17 Dec 1999, accepted on 24 Feb 2000 and first published on 15 Mar 2000


Article type: Communication
DOI: 10.1039/A910232I
Chem. Commun., 2000, 537-538

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    The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxide

    J. Brinksma, R. Hage, J. Kerschner and B. L. Feringa, Chem. Commun., 2000, 537
    DOI: 10.1039/A910232I

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