Issue 23, 2000
From the journal:

Chemical Communications

Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes

S. M. Humayun Kabir†*a  and  Masahiko Iyodaa  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo, Japan

Abstract

The oxidation of cyano-Gilman cuprates, derived from dibromodithienyl sulfide, dibromodithienyldimethylsilane and dibromodithienylmethane, with molecular oxygen furnishes 10-membered ring cyclophanes selectively and an X-ray analysis of cyclophane 9 reveals that it possesses an anti conformation.

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Article information

DOI
https://doi.org/10.1039/B008102G
Article type
Communication
Submitted
06 Oct 2000
Accepted
17 Oct 2000
First published
10 Nov 2000

Chem. Commun., 2000, 2329-2330

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Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes

S. M. H. Kabir and M. Iyoda, Chem. Commun., 2000, 2329 DOI: 10.1039/B008102G

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