Issue 23, 2000
From the journal:

Chemical Communications

A highly convergent synthesis of a branched C-trisaccharide employing a double SmI2-promoted C-glycosylation

Lise Munch Mikkelsen,a   Sussie Lerche Krintel,a   Jesús Jiménez- Barberob  and  Troels Skrydstrup*a  

* Corresponding authors

a Department of Chemistry, University of Aarhus, Langelandsgade 140, Aarhus C, Denmark.
E-mail: ts@kemi.aau.dk;
Fax: Fax: +45 8619 6199

b Instituto de Química Orgánica, CSIC, Juan de la Cierva 3, Madrid, Spain

Abstract

The branched C-trisaccharide analogue of α-D-Man-(1→3)-[α-D-Man-(1→6)]- D-Man has been synthesised by the SmI2-mediated coupling of two mannosyl pyridyl sulfone units to a monosaccharide dialdehyde. This approach represents a highly convergent synthesis of a C-oligosaccharide.

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Article information

DOI
https://doi.org/10.1039/B007117J
Article type
Communication
Submitted
29 Aug 2000
Accepted
10 Oct 2000
First published
09 Nov 2000

Chem. Commun., 2000, 2319-2320

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A highly convergent synthesis of a branched C-trisaccharide employing a double SmI2-promoted C-glycosylation

L. M. Mikkelsen, S. L. Krintel, J. J. Barbero and T. Skrydstrup, Chem. Commun., 2000, 2319 DOI: 10.1039/B007117J

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