Various 1,6-diene palladium(0) monophosphine complexes have been prepared from tmedaPd(CH3)2, PR3, and the corresponding 1,6-diene. These molecularly defined Pd complexes catalyzed the Suzuki coupling of aryl chlorides with phenylboronic acid more efficiently than traditional PdII–PR3 pre-catalysts.
Molecularly defined palladium(0) monophosphine complexes as catalysts for efficient cross-coupling of aryl chlorides and phenylboronic acid1
M. G. Andreu, A. Zapf and M. Beller, Chem. Commun., 2000, 2475 DOI: 10.1039/B006791L
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