Reductive samariation of per-O-trimethylsilyl or benzyl glycopyranosyl iodides in the presence of carbonyl compounds provides the corresponding 1,2-trans-C-glycosyl compounds in good yields.
Synthesis of 1,2-trans C-glycosyl compounds by reductive samariation of glycosyl iodides
N. Miquel, G. Doisneau and J. Beau, Chem. Commun., 2000, 2347 DOI: 10.1039/B006455F
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