A cyclic tetranuclear Cu2Gd2 complex with an S = 8 ground state derived from ferromagnetic spin-coupling between copper(II) and gadolinium(III) ions arrayed alternately

Takafumi Kido; Shigeyuki Nagasato; Yukinari Sunatsuki; Naohide Matsumoto

doi:10.1039/B006445I

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A cyclic tetranuclear Cu₂Gd₂ complex with an S = 8 ground state derived from ferromagnetic spin-coupling between copper(ii) and gadolinium(iii) ions arrayed alternately

Takafumi Kido,^a Shigeyuki Nagasato,^a Yukinari Sunatsuki^a and Naohide Matsumoto*^a

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan.
E-mail: naohide@aster.sci.kumamoto-u.ac.jp

Abstract

A cyclic tetranuclear Cu^II₂Gd^III₂ complex, in which Cu^II and Gd^III ions are arrayed alternately, has an S = 8 spin ground state, due to the ferromagnetic spin coupling between S_Gd = 7/2 and S_Cu = 1/2.

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Supplementary files

Crystal structure data TXT (30K)

Article information

DOI: https://doi.org/10.1039/B006445I
Article type: Communication
Submitted: 07 Aug 2000
Accepted: 27 Sep 2000
First published: 12 Oct 2000

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Chem. Commun., 2000, 2113-2114

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A cyclic tetranuclear Cu₂Gd₂ complex with an S = 8 ground state derived from ferromagnetic spin-coupling between copper(II) and gadolinium(III) ions arrayed alternately

T. Kido, S. Nagasato, Y. Sunatsuki and N. Matsumoto, Chem. Commun., 2000, 2113 DOI: 10.1039/B006445I

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