Issue 22, 2000
From the journal:

Chemical Communications

Oxidation of alkanes with H2O on Ir(acac)3 supported on a carbon fiber-anode

Ichiro Yamanaka,*a   Taishi Furukawaa  and  Kiyoshi Otsukaa  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo, Japan.
E-mail: yamanaka@o.cc.titech.ac.jp

Abstract

Ir(acac)3 supported on a carbon fiber-anode catalyzed the oxidations of alkanes (cyclohexane, n-hexane, adamantane) by generating strong electrophilic oxygen species from H2O at 1.3 V (Ag|AgCl) with high current efficiency, for example, 45% for cyclohexanone formation.

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Article information

DOI
https://doi.org/10.1039/B006107G
Article type
Communication
Submitted
27 Jul 2000
Accepted
06 Oct 2000
First published
31 Oct 2000

Chem. Commun., 2000, 2209-2210

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Oxidation of alkanes with H2O on Ir(acac)3 supported on a carbon fiber-anode

I. Yamanaka, T. Furukawa and K. Otsuka, Chem. Commun., 2000, 2209 DOI: 10.1039/B006107G

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