Issue 20, 2000

Synthesis and structural characterisation of the first hexaphosphastrontocene [Sr(η5-P3C2But2 )2] and its pyrazine adduct

Abstract

Treatment of SrI2 with 2 equivalents of K[P3C2But2] affords the hexaphosphastrontocene [{Sr(η5-P3C2But2 )2}] which is polymeric in the solid state; treatment of this complex with an excess of pyrazine leads to the corresponding Lewis base adduct [{Sr(η5-P3C2But2 )2(μ-C4H4N2)} ] which is also polymeric in the solid state.

Supplementary files

Article information

Article type
Communication
Submitted
20 Jul 2000
Accepted
01 Sep 2000
First published
28 Sep 2000

Chem. Commun., 2000, 2027-2028

Synthesis and structural characterisation of the first hexaphosphastrontocene [Sr(η5-P3C2But2 )2] and its pyrazine adduct

M. D. Francis, P. B. Hitchcock and J. F. Nixon, Chem. Commun., 2000, 2027 DOI: 10.1039/B005855F

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