Issue 20, 2000

Pyrazole and benzothiazole palladacycles: stable and efficient catalysts for carbon–carbon bond formation

Abstract

Cyclopalladated phosphine free pyrazole complexes 1 and benzothiazole complexes 2 are excellent catalysts for the Heck vinylation of aryl iodides and termolecular queuing cascades, leading to turnover numbers of >106 in some cases, at moderate temperatures; these catalysts show high thermal stability and are not sensitive to moisture and air.

Article information

Article type
Communication
Submitted
01 Aug 2000
Accepted
11 Sep 2000
First published
02 Oct 2000

Chem. Commun., 2000, 2053-2054

Pyrazole and benzothiazole palladacycles: stable and efficient catalysts for carbon–carbon bond formation

X. Gai, R. Grigg, M. I. Ramzan, V. Sridharan, S. Collard and J. E. Muir, Chem. Commun., 2000, 2053 DOI: 10.1039/B005452F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements