Issue 19, 2000
From the journal:

Chemical Communications

Unexpected synthesis of (bis(diphenylphosphinoyl)ethane)·2(2,2- dihydroperoxypropane) 1∶2 adduct: a new route to stable organic dihydroperoxides

Claudio Pettinari,*a   Fabio Marchetti,a   Augusto Cingolani,a   Andrei Drozdovb  and  Sergei Troyanov†b  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università degli Studi, via S. Agostino 1, Camerino, Italy.
E-mail: pettinar@camserv.unicam.it

b Moscow State University, Chemistry Department, Vorobjevy Gory, Moscow, Russia.
E-mail: troyanov@thermo.chem.msu.ru

Abstract

By reaction of hydrogen peroxide and bis(diphenylphosphino)ethane in acetone, the 1∶2 adduct (bis(diphenylphosphinoyl)ethane)·2(2,2-dihydroperoxypropane) (dppeO2)· 2[Me2C(OOH)2], stabilized by H-bonding between Me2- C(OOH)2 and dppeO2, was rapidly obtained in high yields in the presence of R2SnCl2 (R = Me or Bun).

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Article information

DOI
https://doi.org/10.1039/B005221N
Article type
Communication
Submitted
27 Jun 2000
Accepted
22 Aug 2000
First published
19 Sep 2000

Chem. Commun., 2000, 1901-1902

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Unexpected synthesis of (bis(diphenylphosphinoyl)ethane)·2(2,2- dihydroperoxypropane) 1∶2 adduct: a new route to stable organic dihydroperoxides

C. Pettinari, F. Marchetti, A. Cingolani, A. Drozdov and S. Troyanov, Chem. Commun., 2000, 1901 DOI: 10.1039/B005221N

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