An electron-deficient iron porphyrin complex catalyzes the epoxidation of olefins by tert-alkyl hydroperoxides via radical-free oxidation reactions in aprotic solvent; the epoxidation reactions were markedly influenced by reaction temperature and high yields of epoxide products were obtained with retention of stereospecificity at low temperature.
Temperature effect on the epoxidation of olefins by an iron(III) porphyrin complex and tert-alkyl hydroperoxides
W. Nam, S. Oh, M. H. Lim, M. Choi, S. Han and G. Jhon, Chem. Commun., 2000, 1787 DOI: 10.1039/B005162O
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