[3,3]-Claisen rearrangements allowed the conversion of a readily available allylic difluorophosphonate to nucleic acid and inositol phosphate-related products via epoxide cyclisation or ring closing metathesis respectively.
A rearrangement-based approach to secondary difluorophosphonates
A. H. Butt, J. M. Percy and N. S. Spencer, Chem. Commun., 2000, 1691 DOI: 10.1039/B005110L
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