Issue 19, 2000
From the journal:

Chemical Communications

Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes

Natalia Morlender-Vais,a   Nicka Solodovnikovaa  and  Ilan Marek*a  

* Corresponding authors

a Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa, Israel.
E-mail: chilanm@tx.technion.ac.il

Abstract

Treatment of δ- and γ-functionalized monosubstituted alkynes with diisopropoxy(η2-propene)titanium induces an intramolecular cyclisation to afford the 4- and 5-membered cycloalkanols in good overall yields.

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Article information

DOI
https://doi.org/10.1039/B005027J
Article type
Communication
Submitted
20 Jun 2000
Accepted
20 Jul 2000
First published
14 Sep 2000

Chem. Commun., 2000, 1849-1850

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Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes

N. Morlender-Vais, N. Solodovnikova and I. Marek, Chem. Commun., 2000, 1849 DOI: 10.1039/B005027J

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