Issue 19, 2000

The characterisation and reactivity of (η5-C5H5)M(CO)3(Xe) (M = Nb or Ta) in solution at room temperature

Abstract

Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)3(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)3(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)3(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

Article information

Article type
Communication
Submitted
16 Jun 2000
Accepted
04 Aug 2000
First published
11 Sep 2000

Chem. Commun., 2000, 1841-1842

The characterisation and reactivity of (η5-C5H5)M(CO)3(Xe) (M = Nb or Ta) in solution at room temperature

D. C. Grills, G. I. Childs and M. W. George, Chem. Commun., 2000, 1841 DOI: 10.1039/B004843G

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