Issue 17, 2000

Homogeneously catalyzed, chelate assisted hydrogenolysis of an

Abstract

Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butylphosphinomethyl)-2,4,6-tri methylbenzene (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C–N single bond.

Article information

Article type
Communication
Submitted
15 Jun 2000
Accepted
12 Jul 2000
First published
04 Aug 2000

Chem. Commun., 2000, 1603-1604

Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond

M. Gandelman and D. Milstein, Chem. Commun., 2000, 1603 DOI: 10.1039/B004820H

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