Issue 16, 2000
From the journal:

Chemical Communications

Asymmetric synthesis of indolizidine alkaloids by ring-closing–ring-opening metathesis

Huib Ovaa,a   Roland Stragies,b   Gijs A. van der Marel,a   Jacques H. van Booma  and  Siegfried Blechert*b  

* Corresponding authors

a Leiden Institute of Chemistry, Gorlaeus Laboratories, P.O. Box 9502, 2300 RA, Leiden, The Netherlands

b Institut für Organische Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623, Berlin, Germany.
E-mail: Blechert@chem.tu-berlin.de

Abstract

Asymmetric Pd(0) catalyzed allylic amination followed by a Ru catalyzed RCM–ROM sequence converted an easily accessible racemic cyclopentenol 2 to the functionalized tetrahydropyridine 9 which can be used for the asymmetrical synthesis of indolizidine 13.

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Article information

DOI
https://doi.org/10.1039/B004106H
Article type
Communication
Submitted
19 May 2000
Accepted
21 Jun 2000
First published
19 Jul 2000

Chem. Commun., 2000, 1501-1502

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Asymmetric synthesis of indolizidine alkaloids by ring-closing–ring-opening metathesis

H. Ovaa, R. Stragies, G. A. van der Marel, J. H. van Boom and S. Blechert, Chem. Commun., 2000, 1501 DOI: 10.1039/B004106H

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