Enantioselective hydroboration of olefins catalysed bycationic rhodium complexes of2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene

Mary McCarthy; Mark W. Hooper; Patrick J. Guiry

doi:10.1039/B004014M

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Enantioselective hydroboration of olefins catalysed by cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthaleneThis compound has previously been published under the name 2-phenyl-quinazolinap.

Mary McCarthy,^a Mark W. Hooper^b and Patrick J. Guiry*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University College Dublin, Belfield, Dublin, Ireland

^b Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: p.guiry@ucd.ie

Abstract

Cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene catalyse the hydroboration of indene, tetrahydronaphthalene and a range of styrenes in high yields, regioselectivities and with enantiomer excesses of up to 97%

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Article information

DOI: https://doi.org/10.1039/B004014M
Article type: Communication
Submitted: 09 May 2000
Accepted: 07 Jun 2000
First published: 29 Jun 2000

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Chem. Commun., 2000, 1333-1334

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Enantioselective hydroboration of olefins catalysed by cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene

M. McCarthy, M. W. Hooper and P. J. Guiry, Chem. Commun., 2000, 1333 DOI: 10.1039/B004014M

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