Issue 16, 2000
From the journal:

Chemical Communications

A new simple synthesis of cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes from ketones and tetraphosphorus decasulfide

Kentaro Okuma,*a   Shinji Shibata,a   Kosei Shiojia  and  Yoshinobu Yokomorib  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Fukuoka University, Jonan-ku, Fukuoka, Japan.
E-mail: kokuma@fukuoka-u.ac.jp

b Department of Applied Chemistry, National Defense Academy, Hashirimizu, Yokosuka, Japan

Abstract

The reaction of pivalophenones with tetraphosphorus decasulfide afforded cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes, which equilibrated to give other isomers in refluxing toluene via thiopivalophenones and thiopivalophenone S-sulfides.

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Article information

DOI
https://doi.org/10.1039/B004013O
Article type
Communication
Submitted
18 May 2000
Accepted
30 Jun 2000
First published
25 Jul 2000

Chem. Commun., 2000, 1535-1536

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A new simple synthesis of cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes from ketones and tetraphosphorus decasulfide

K. Okuma, S. Shibata, K. Shioji and Y. Yokomori, Chem. Commun., 2000, 1535 DOI: 10.1039/B004013O

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