A rationally designed chiral auxiliary for hydroxylated dienes results in stereocontrolled Diels–Alder cycloadditions under purely thermal conditions.
Asymmetric Diels–Alder chemistry based on a new chiral auxiliary for 1-hydroxy substituted dienes
P. Garner, J. T. Anderson and R. A. Turske, Chem. Commun., 2000, 1579 DOI: 10.1039/B003713N
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