Issue 15, 2000
From the journal:

Chemical Communications

Sol–gel entrapped TEMPO for the selective oxidation of methyl α-d-glucopyranosideElectronic Supplementary Information (ESI) available: details of the preparation of a typical catalyst and its use in the oxidation of MGP to the corresponding uronate. See http://www.rsc.org/suppdata/cc/b0/b003096l/

Rosaria Ciriminna,a   Jochanan Blum,b   David Avnirb  and  Mario Pagliaro*a  

* Corresponding authors

a Institute of Chemistry and Technology of Natural Products, CNR, via Ugo La Malfa 153, 90146, Palermo, Italy

b Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.
E-mail: pagliaro@ictpn.pa.cnr.it

Abstract

The sol–gel entrapment of TEMPO within a silica matrix yields an efficient and recyclable catalytic system for the selective oxidation of methyl α-D-glucopyranoside (MGP) in water with NaOCl as primary oxidant, thus opening the way to the heterogeneous catalysis of the conversion of sugars into valuable uronates.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B003096L
Article type
Communication
Submitted
17 Apr 2000
Accepted
20 Jun 2000
First published
19 Jul 2000

Chem. Commun., 2000, 1441-1442

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Sol–gel entrapped TEMPO for the selective oxidation of methyl α-D-glucopyranoside

R. Ciriminna, J. Blum, D. Avnir and M. Pagliaro, Chem. Commun., 2000, 1441 DOI: 10.1039/B003096L

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