Issue 12, 2000

Nitrous oxide decomposition active site on Ni–MgO catalysts characterized by X-ray absorption fine structure spectroscopy

Abstract

A contracted Ni2+ coordination site distorted in the direction of Ni⋯Mg and Ni⋯Ni was found to be responsible for catalytic N2O decomposition when Ni2+ is diluted in a MgO matrix (Ni2+/Mg2+ atomic ratio ≈ 1.0) based on a local structure study by nickel K-edge X-ray absorption fine structure spectroscopy.

Article information

Article type
Communication
Submitted
06 Apr 2000
Accepted
08 May 2000
First published
26 May 2000

Chem. Commun., 2000, 1053-1054

Nitrous oxide decomposition active site on Ni–MgO catalysts characterized by X-ray absorption fine structure spectroscopy

Y. Izumi, T. Shimizu, T. Kobayashi and K. Aika, Chem. Commun., 2000, 1053 DOI: 10.1039/B002773L

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