The Ti-mediated allylsilane addition to bicyclic lactams occurs with high stereoselectivity and combined with a ring closure metathesis provides the title compounds in high ee.
Concise synthesis of indolizidines: total synthesis of (−)-coniceine
M. D. Groaning and A. I. Meyers, Chem. Commun., 2000, 1027 DOI: 10.1039/B002621M
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