A new synthesis of [2,3]naphthoporphyrins using 4,9-ethano-2H-benz[f]isoindole as a synthon of 2H-benz[f]- isoindole is described; soluble precursors of [2,3]naphthoporphyrins are converted into insoluble [2,3]naphthoporphyrins by simply heating at 290 °C.
S. Ito, N. Ochi, H. Uno, T. Murashima and N. Ono, Chem. Commun., 2000, 893 DOI: 10.1039/B002213F
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