Issue 9, 2000
From the journal:

Chemical Communications

Unusual high nuclearity and pseudo-tetrahedral Zn8O13 core found in a self-assembled complex

Jesús Sanmartín,a   Manuel R. Bermejo,*a   Ana M. García-Deibea  and  Antonio L. Llamas-Saizb  

* Corresponding authors

a Departamento de Química Inorgánica, Facultade de Química, Campus Sur, Universidade de Santiago de Compostela, Santiago de Compostela, Galicia, Spain.
E-mail: qimb45@uscmail.usc.es

b Unidade de Raios X. Vicerrectorado de Investigación, Universidade de Santiago de Compostela, Campus Sur, Santiago de Compostela, Galicia, Spain

Abstract

An electrochemical synthesis yielded powdery [Zn2(L)(H2O)]n [H4L = N,N′-bis(3-hydroxysalicylidene)-1,4-diaminobutane] and crystals of [Zn8(L)4(H2O)3]·H2 O· 0.25MeCN, whose X-ray crystal structure shows an unusual pseudo-tetrahedral Zn8O13 core assembled by thirteen μ-phenoxo bridges, where Zn(II) ions are pentaco-ordinated.

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Article information

DOI
https://doi.org/10.1039/B001368O
Article type
Communication
Submitted
18 Feb 2000
Accepted
23 Mar 2000
First published
18 Apr 2000

Chem. Commun., 2000, 795-796

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Unusual high nuclearity and pseudo-tetrahedral Zn8O13 core found in a self-assembled complex

J. Sanmartín, M. R. Bermejo, A. M. García-Deibe and A. L. Llamas-Saiz, Chem. Commun., 2000, 795 DOI: 10.1039/B001368O

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