Tesselation of new supramolecular motifs of the tetra(4-carboxyphenyl)porphyrin building blocks by metal ion templates has been demonstrated in crystals, characterizing the square-planar [Na+·(–COOH)4·X− ] and the tetrahedral [Zn2+·(–COOH)2·(–COO −)2] molecular recognition elements for effective multiporphyrin assembly.
New effective synthons for supramolecular self-assembly
of meso-carboxyphenylporphyrins
Y. Diskin-Posner, S. Dahal and I. Goldberg, Chem. Commun., 2000, 585 DOI: 10.1039/B001189O
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