In the neutron diffraction study of the 1∶1 adduct 2-methylpyridine–pentachlorophenol, a very short O–H⋯N hydrogen bond is found with a sharply defined proton position, and distances of O–H = 1.068(7), H⋯N = 1.535(7) and O⋯N = 2.588(3) Å; the bond order of H⋯N is about 0.24 valence units.
Neutron diffraction study of a very short O–H⋯N hydrogen bond: crystalline adduct of 2-methylpyridine and pentachlorophenol
T. Steiner, C. C. Wilson and I. Majerz, Chem. Commun., 2000, 1231 DOI: 10.1039/B001179G
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