The synthesis and structural characterisation of a novel metal polyhedron is reported, involving chromium(III) and isobutyrate; comparison of this product with those obtained using different carboxylates suggests that the leaving group—which can be carboxylate, water or both—strongly influences the structure found.
A novel dodecanuclear chromium(III) cage: structural control by choice of leaving group
S. Parsons, A. A. Smith and R. E. P. Winpenny, Chem. Commun., 2000, 579 DOI: 10.1039/B001140L
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