Issue 11, 2000
From the journal:

Chemical Communications

N[double bond, length half m-dash]N bond cleavage of azobenzene through Pt/TiO2 photocatalytic reduction

Hiroaki Tada,*a   Masanobu Kubo,b   Yoichi Inubushic  and  Seishiro Itob  

* Corresponding authors

a Environmental Science Research Institute, Kinki University, 3-4-1, Kowakae, Higashi-Osaka, 577-8502, Japan.
E-mail: h-tada@apsrv.apch.kindai.ac.jp

b Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1, Kowakae, Higashi-Osaka, 577-8502, Japan

c Fuji Pigment Co. Ltd., 2-23-2, Obana, Kawanishi, Hyogo 606-0015, Japan

Abstract

TiO2 photocatalytic 2e−-reduction of azobenzene to hydrazobenzene is found to occur at λex > 300 nm while loading of nanometer-sized Pt particles on TiO2 induces N[double bond, length half m-dash]N bond cleavage via 4e−-reduction; only photoisomerization occurs in the absence of TiO2.

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Article information

DOI
https://doi.org/10.1039/B001062F
Article type
Communication
Submitted
07 Feb 2000
Accepted
27 Apr 2000
First published
17 May 2000

Chem. Commun., 2000, 977-978

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N[double bond, length half m-dash]N bond cleavage of azobenzene through Pt/TiO2 photocatalytic reduction

H. Tada, M. Kubo, Y. Inubushi and S. Ito, Chem. Commun., 2000, 977 DOI: 10.1039/B001062F

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