Crystal structure and magnetic properties of a new two-dimensional cyano-bridged bimetallic assembly [NiL′]3[Cr(CN)5(NO)]2·10H 2O (L′ = 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)
Abstract
A new cyano-bridged Ni(II)–Cr(I) complex, [NiL′]3[Cr(CN)5(NO)]2·10H 2O (L′ = 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane) with a honeycomb molecular structure, displays a long-range magnetic ordering at Tc = 4.5 K.