Issue 13, 2000
From the journal:

Chemical Communications

The addition of isocyanides to ReS4−: [3 + 1] cycloaddition to S[double bond, length half m-dash]M[double bond, length half m-dash]S

Daniel E. Schwarza  and  Thomas B. Rauchfuss*a  

* Corresponding authors

a School of Chemical Sciences and the Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL, USA.
E-mail: rauchfuz@uiuc.edu

Abstract

Isocyanides undergo [3 + 1] cycloadditions to ReS4− to give dithiocarboimidate derivatives, Re(S)(S4)(S2CNR)− and Re2S5(S2CNR)22− , which undergo S-atom transfer and, in the case of the monometallic species, N-alkylation.

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Article information

DOI
https://doi.org/10.1039/B000932F
Article type
Communication
Submitted
27 Jan 2000
Accepted
03 May 2000
First published
08 Jun 2000

Chem. Commun., 2000, 1123-1124

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The addition of isocyanides to ReS4−: [3 + 1] cycloaddition to S[double bond, length half m-dash]M[double bond, length half m-dash]S

D. E. Schwarz and T. B. Rauchfuss, Chem. Commun., 2000, 1123 DOI: 10.1039/B000932F

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