Issue 7, 2000
From the journal:

Chemical Communications

Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(iii) complex

Choong Eui Song,*a   Eun Joo Roh,a   Byoung Mook Yu,b   Dae Yoon Chi,b   Su Chang Kimc  and  Kee-Jung Leec  

* Corresponding authors

a Life Sciences Division, Korea Institute of Science and Technology, PO Box 131, Cheongryang, Seoul, 130-650, Korea.
E-mail: s1673@kistmail.kist.re.kr

b Department of Chemistry, Inha University, 253 Yonghyun-Dong, Nam-Ku, Inchon, 402-751, Korea

c Division of Chemical Engineering and Industrial Chemistry, Hanyang University, Seoul, 133-791, Korea

Abstract

Excellent enantioselectivity (e.g. 92% ee for 2,2-dimethylchromene) has been achieved in heterogeneous asymmetric epoxidation using a polymer-bound (pyrrolidine salen)-manganese(III) complex; however, this polymeric catalyst underwent partial decomposition under epoxidation conditions.

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Article information

DOI
https://doi.org/10.1039/B000876L
Article type
Communication
Submitted
01 Feb 2000
Accepted
06 Mar 2000
First published
22 Mar 2000

Chem. Commun., 2000, 615-616

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Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(III) complex

C. E. Song, E. J. Roh, B. M. Yu, D. Y. Chi, S. C. Kim and K. Lee, Chem. Commun., 2000, 615 DOI: 10.1039/B000876L

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