When parahydrogen induced polarisation is used to examine hydrogenation reactions involving [Rh(μ-Cl)(PPh3)2]2 and RhCl(CO)(PMe3)2, binuclear dihydride complexes are detected, characterised, and shown to be capable of alkene hydrogenation.
Characterisation and kinetic behaviour of H2Rh(PPh3)2(μ-Cl)2Rh(PPh 3)(alkene) and related binuclear complexes detected during hydrogenation studies involving parahydrogen induced polarisation
S. A. Colebrooke, S. B. Duckett and J. A. B. Lohman, Chem. Commun., 2000, 685 DOI: 10.1039/B000607F
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