Synthesis and structure of the first boron-bridged constrained geometry complexesElectronic supplementary information (ESI) available: experimental and polymerisation studies. See http://www.rsc.org/suppdata/cc/b0/b000380h/

Abstract

In the course of investigations on new Ziegler–Natta-analogous catalyst systems, the first ‘constrained geometry’ complexes of titanium with a bridging boron atom have been conveniently obtained by a high yield synthesis and were structurally characterized.