High turnover number of γ-SiW10{MnIII(OH2)}2O386− for oxygenation of cyclohexane with 1 atm molecular oxygen

Tetsuya Hayashi; Asako Kishida; Noritaka Mizuno

doi:10.1039/A910334L

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High turnover number of γ-SiW₁₀{Mn^III(OH₂)}₂O₃₈⁶⁻ for oxygenation of cyclohexane with 1 atm molecular oxygenElectronic supplementary information (ESI) available: preparation and characterization of polyoxometalates. See http://www.rsc.org/suppdata/cc/a9/a910334l/

Tetsuya Hayashi,^a Asako Kishida^a and Noritaka Mizuno*^a

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan.
E-mail: tmizuno@mail.ecc.u-tokyo.ac.jp

Abstract

An all-inorganic oxo-bridged dimanganese-containing silicotungstate, γ-SiW₁₀{Mn^III(OH₂)}₂O₃₈⁶⁻, showed the highest turnover number of 789 among various metal-substituted silicotungstates for the oxygenation of cyclohexane with 1 atm molecular oxygen; this is the highest level when compared with other catalysts reported so far.

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Supplementary files

Preparation and characterization of polyoxometalates DOC (35K)

Article information

DOI: https://doi.org/10.1039/A910334L
Article type: Communication
Submitted: 24 Dec 1999
Accepted: 03 Feb 2000
First published: 24 Feb 2000

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Chem. Commun., 2000, 381-382

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High turnover number of γ-SiW₁₀{Mn^III(OH₂)}₂O₃₈⁶⁻ for oxygenation of cyclohexane with 1 atm molecular oxygen

T. Hayashi, A. Kishida and N. Mizuno, Chem. Commun., 2000, 381 DOI: 10.1039/A910334L

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