The hexakis(TTF) derivative 3 has been synthesised in 89% yield by six-fold reaction of the thiolate anion of reagent 2 with hexakis(bromomethyl)benzene: the solution electrochemistry of 3 shows sequential formation of the hexa- (radical cation) and the dodecacation species, and spectroelectrochemistry shows interacting radical cations; the X-ray crystal structure of 3 is reported.
A novel hexakis(tetrathiafulvalene) derivative: synthesis, structure and electrochemical properties
C. A. Christensen, M. R. Bryce, A. S. Batsanov and J. Becher, Chem. Commun., 2000, 331 DOI: 10.1039/A909882H
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