Issue 4, 2000

Hydrogen bonding networks and anion coordination in (η6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors

Abstract

A chloride selective amide cleft molecule 2 containing two Cr(CO)3 moieties has been synthesised by condensation of (η6-aniline)Cr(CO)3 3 with isophthaloyl dichloride; the X-ray crystal structure of 2 contains a network of Cr–CO···HN hydrogen bonds giving rise to an extended three-dimensional coordination array; the X-ray crystal structure of (η6-aniline)Cr(CO)3 3 has been re-determined and found to contain bifurcated amine NH···OC–Cr hydrogen bonds.

Supplementary files

Article information

Article type
Communication
Submitted
15 Dec 1999
Accepted
12 Jan 2000
First published
03 Feb 2000

Chem. Commun., 2000, 275-276

Hydrogen bonding networks and anion coordination in (η6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors

S. Camiolo, S. J. Coles, P. A. Gale, M. B. Hursthouse, T. A. Mayer and M. A. Paver, Chem. Commun., 2000, 275 DOI: 10.1039/A909861E

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