Issue 4, 2000
From the journal:

Chemical Communications

Hydrogen bonding networks and anion coordination in (η6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors

Salvatore Camiolo,a   Simon J. Coles,a   Philip A. Gale,*a   Michael B. Hursthouse,a   Thomas A. Mayera  and  Michael A. Paver*a  

* Corresponding authors

a Department of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: philip.gale@soton.ac.uk or m.a.paver@soton.ac.uk

Abstract

A chloride selective amide cleft molecule 2 containing two Cr(CO)3 moieties has been synthesised by condensation of (η6-aniline)Cr(CO)3 3 with isophthaloyl dichloride; the X-ray crystal structure of 2 contains a network of Cr–CO···HN hydrogen bonds giving rise to an extended three-dimensional coordination array; the X-ray crystal structure of (η6-aniline)Cr(CO)3 3 has been re-determined and found to contain bifurcated amine NH···OC–Cr hydrogen bonds.

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Article information

DOI
https://doi.org/10.1039/A909861E
Article type
Communication
Submitted
15 Dec 1999
Accepted
12 Jan 2000
First published
03 Feb 2000

Chem. Commun., 2000, 275-276

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Hydrogen bonding networks and anion coordination in (η6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors

S. Camiolo, S. J. Coles, P. A. Gale, M. B. Hursthouse, T. A. Mayer and M. A. Paver, Chem. Commun., 2000, 275 DOI: 10.1039/A909861E

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